Pengaruh Penambahan Konsentrasi Ag2S Terhadap Komposit Konduktor (Ag2S)x(Na3PO4)1-x (x = 0,1 - 0,5 )

Safei Purnama, Patricius Purwanto, Grace Tj. Sulungbudi


Komposit konduktor (Ag2S)x(Na3PO4)1-x dibuat dengan metalurgi serbuk dengan mencampurkan serbuk Ag2S dengan Na3PO4, dikompaksi dengan tekanan 48,26.106 N/m2 dan diameter 1,5.10-2 m. Komposit konduktor (Ag2S)x(Na3PO4)1-x dilakukan pemanasan pada suhu 150 °C selama 5 jam. Penentuan struktur kristal (Ag2S)x(Na3PO4)1-x dilakukan dengan teknik difraksi sinar- x. Analisis puncak difraksi sinar-x pada komposit konduktor (Ag2S)x(Na3PO4)1-x menunjukkan struktur Ag2S dan Na3PO4. Pengukuran konduktivitas komposit konduktor (Ag2S)x(Na3PO4)1-x dilakukan dengan alat LCR-meter pada frekuensi 0,1 Hz sampai dengan 100 kHz. Konduktivitas komposit konduktor (Ag2S)x(Na3PO4)1-x naik dan impedansinya turun seiring dengan naiknya konsentrasi Ag2S. Analisis morfologi permukaan komposit konduktor (Ag2S)x(Na3PO4)1-x dilakukan dengan mikroskop elektron, hasil menunjukkan terjadi perubahan seiring dengan bertambahnya konsentrasi Ag2S. 


Komposit, Difraksi sinar-x; Konduktivitas; Struktur mikro

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Blanton, T., S. Misture, N. Dontula, and S. Zdzieszynski. 2011. In situ high temperature X-ray Diffraction characterization of silver sulfide, Ag2S. JCPDs-International Centre for Diffraction Data 26 : 114-118.

Burbano, J.C., R.A. Vargas, D. Pena Lara, C. A. Lozano Z, and H. Correa. 2009. Defect interaction and solid elelctrolite transition in Agi-based material. Solid State ionic 180 : 1553-1557.

Han, Y., M. Zou, Weiqiangly, Y. Mao, W. Wang, and W. D. He. 2016. Three dimensional ionic conduction in the strained electrolytes of solid oxide fuel cells. Journal .Appied .Physics.119 :174904.

Hu, H., J. Ding, S. Zhang, Y. Lin, L. Bai, and N.

Yuan. 2013. Photodeposition of Ag2S on TiO2 nanorod arrays for quantum dot sensitized solar cells. Nanoscale Research Letters 8 :10.

Ihsan, M., E. Kartini, and Y. Yulizar. 2008. Sintesis elektrolit padat berbasis gelas lithium (Ag2S)x(LiPO3)1-x. Jurnal Sains Materi Indonesia (Edisi Khusus) : 176- 180.

Jadhav, U.M., S.N. Patel, and R.S. Patil. 2013. Synthesis of silver sulphide nanoparticles by modified chemical route for solar cell application. Journal of Chemistry Science 3 : 69-74.

Kobayashi, M. 2006. Electronic structure of superinic conductor. Phys. of Solid State Ionic 2006 : 1-5

Krylova, V. and N. Dukstiene. 2013. Synthesis and characterization of Ag2S layers formed on polypropylene. Journal of Chemistry 2013 : 1-11.

Padma, P. and S. Yashonath. 2006. ionic condition in the solid state. Journal Chem.Sci.118 : 135-154.

Rajbhandari, A., K. Manandhar, and R. R. Pradhananga. 2013. Preparation and characterization of home made silver sulphide based chloride selective electrode. IJCPS 1(8): 492-496.

Raykovic, V. , D. Bozic, M. Popovic, and M.T. Jovanovic. 2009. The influence of powder particle size on properties of Cu-Al2O3 composites. Sci. of Sintering.41 : 185- 192.

Shukla, N., A. K. Thakur, A. Shukla, and D. T.

Mark. 2014. Ion conduction mechanism in solid polymer electrolyte : an applicability of almond-west formalism. Int. J. Electrochem. Science 9 : 7644-7659.

Sun, J. C., Y. Xu, R. Wang, Z. Qiu, and L. Xing. 2013. Influences of temperature on the conductive properties of single crystal C12A7: e-. Int. J. Electrochem. Sci. 8 : 10122 – 10128.

Yang, M. and J. Hou. 2012. Membranes in lithium ion batteries. Membranes 2 : 367-383.



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